Bronze

Bronze is a metal alloy composed of copper and tin. A unique material of great historical interest, still finds a wide range of applications today . It was probably discovered before 3000 bc, though its use in artifacts did not become common until much later.

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What is Bronze?

Bronze is the name given to alloys of copper; with the exception of alloys of copper with zinc as the next-most-populous constituent – which are known as brass. Bronze can include alloys of copper with numerous metallic and non-metallic elements, including tin, aluminium, manganese, and silicon; and sometimes a lesser amount of zinc.


Image result for bronzoBronze “ore” can occur naturally, where, for example, natural deposits of copper and tin occur together – but this is very rare. Historically, bronze could only be made when trade allowed for an exchange of copper and tin metals or ores.

Info source: https://www.quora.com/What-is-bronze-and-how-is-it-made

Image source: https://it.wikipedia.org/wiki/Bronzo

How does bronze form?

Copper is made from copper ore by a process known as smelting – heating the ore to a very high temperature, and removing impurities. Other alloy components can also be added to the molten copper at this time, where they melt and combine with the molten copper. In modern times, this is done with extreme precision, to ensure the consistency of bronzes, as even small variations in the “recipe” of alloys can result in very different physical, casting, and aesthetic qualities.

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Info source: https://www.quora.com/What-is-bronze-and-how-is-it-made

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What are the type of Bronze?

  • Commercial bronze (90% copper and 10% zinc) and architectural bronze (57% copper, 3% lead, 40% zinc) are more properly regarded as brass alloys because they contain zinc as the main alloying ingredient. They are commonly used in architectural applications.

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  • Bismuth bronze is a bronze alloy with a composition of 52% copper, 30% nickel, 12% zinc, 5% lead, and 1% bismuth. It is able to hold a good polish and so is sometimes used in light reflectors and mirrors.
  • Plastic bronze is bronze containing a significant quantity of lead which makes for improved plasticity possibly used by the ancient Greeks in their ship construction.
  • Silicon bronze has a composition of Si: 2.80–3.80%, Mn: 0.50–1.30%, Fe: 0.80% max., Zn: 1.50% max., Pb: 0.05% max., Cu: balance.

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  • Other bronze alloys include aluminium bronze, phosphor bronze, manganese bronze, bell metal, arsenical bronze, speculum metal and cymbal alloys.

Info source: https://en.wikipedia.org/wiki/Bronze#Composition.2C_alloys

Image source: http://www.sdalloys.com/commercialbronze.php

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What are the stages of bronze working?

  • Make the Metal Hot: Heat the bronze to about 2,150 degrees Fahrenheit.

Pouring the Mold

  • Pouring the Mold: Slowly fill the mold

  • Clean Casting: When cool, bronze will easily separate from the sand but you’ll need to clean it up a bit and maybe fix some imperfections in the casting.

  • Fabricating: Beginning to fabricate the geometry around the casting for a wall hanging sculpture.

  • Applying a Hot Patina: Clean the metal and then apply heat and chemicals: in this case ferric nitrate, cuprice nitrate and ammonium sulfide.

Applying a Hot Patina

  • Finished Piece: Wax the sculpture with a couple coats of carnuba based wax.

Info and image source: http://www.instructables.com/id/Making-a-sand-cast-bronze-sculpture/

What are Bronze characteristics?

  • Alloy Composition: Ancient bronze was usually made up of copper, tin and small amounts of noble metals or lead. The amount of tin could reach 40 percent but classic bronze alloy and today’s commercial bronze are 10 percent tin and 90 percent copper. Alloys with more tin are technically brass alloys. Manganese is added to bronze used for ships’ propellers because it resists saltwater corrosion. Iron, nickel, silicon and aluminum are added for strength in tools because bronze will not make a spark when struck.
  • Hardness and Strength: Bronze strength depends on the composition of the alloy and ranges from 35,000 pounds per square inch (psi) tensile strength for standard bronze through 85,000 psi for aluminium bronze to 119,000 psi for manganese bronze. The yield strength ranges from 32,000 to 68,000 psi. Brinell hardness measures from 65 to 225. Ancient bronze was at the lower end of these figures but modern aluminum and manganese bronzes are used in marine fittings, bearings and pumps where high strength and hardness are required.
  • Melting Point: Copper has a melting point of 2200 degrees Fahrenheit and tin 450 degrees Fahrenheit. Depending on the amount of tin and copper in the alloy, the melting point of bronze falls somewhere between the two. Typical ancient bronze had a melting point of about 2000 degrees Fahrenheit, which was near the top of the temperature range that could be achieved in prehistoric furnaces. The miners first had to melt the copper to make the bronze, and then the metalworkers melted the bronze to cast the shapes they wanted.

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  • Resistance to Corrosion: Natural bronze is a salmon-colored metal but statues and other outdoor artifacts quickly develop a patina, which protects the bronze from further rapid deterioration. The patina can vary in color from lime green to dark brown, and bronze is sometimes treated at the foundry to develop a patina before it is delivered. While bronze is resistant to normal atmospheric agents, the presence of sulphur or chlorine in the atmosphere will accelerate deterioration.

 

Info source: http://sciencing.com/characteristics-bronze-metals-8162597.html

Image source: https://www.copper.org/applications/plumbing/techcorner/designing_piping_systems.html

How was Bronze used throughout history?

Bronze was developed about 3500 BC by the ancient Sumerians in the Tigris-Euphrates Valley. Historians are unsure how this alloy was discovered, but believe that bronze may have first been made accidentally when rocks rich in copper and tin were used to build campfire rings.
Around 3000 BC, bronze-making spread to Persia, where bronze objects such as ornaments, weapons, and chariot fittings have been found. Bronzes appeared in both Egypt and China around 2000 BC. The earliest bronze castings (objects made by pouring liquid metal into molds) were made in sand, and this method is sometimes still used, even for casting bells.

Image result for persian bronze
At first, copper-arsenic alloys were used, but only for a short while. One disadvantage of this alloy was that the fumes emitted by arsenic during smelting tended to kill the metalsmiths.
Eventually, tin was found to be an ideal alloying agent for copper. The optimum ratio is about 10 to 20% tin to copper. The melting point of bronze is 950 deg. C, compared to 1084 deg. C for pure copper.

Info source: http://www.russianbells.com/founding/bronzehistory.html

image source: http://www.ancientresource.com/lots/persia.html

Where can we find bronze today?

After its discovery (for the Middle East, around 700 BC) iron, and later steel, quickly replaced bronze in the ancient world as the metal of choice for weaponry and industry because it is harder and more durable.

Image result for bronze clockToday, bronze  is used for making products ranging from household items such as doorknobs, drawer handles, clocks, and sculpture, but it is also still used in some industrial applications, such as engine parts, bearings, and wire. And of course, it is used in bells.

Info source:http://www.russianbells.com/founding/bronzehistory.html

image source: http://www.horchow.com/Bronze-Clock/cprod107960005/p.prod

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