Limestone

Limestone is a sedimentary rock,  formed from small pressurized particles of rocks and stones. Sedimentary rocks are very important because they often contain fossils and give us indications about past ages. 

Limestone
Limestone

image source: http://www.dkfindout.com/uk/earth/rocks-and-minerals/sedimentary-rocks/


what is limestone?

Limestone is a sedimentary rock consisting by 50% of calcium carbonate(CaCO3) in the form of the mineral calcite. its origins can be traced back to either chemical or biochemical processes that occurred in the past ( hundreds of millions of years ago). It usually forms in clear, warm, shallow marine waters from the accumulation of shell, coral, algal, and fecal debris. However it can also be formed by the precipitation of calcium carbonate from lake or ocean water. Because it is often formed from shells or bones, it has a light tone color like white, tan, or gray; Therefore his color is influenced by sediments in the mixture.


Organic limestone, made from old shells.
Organic limestone, made from old shells.

image source: http://madteaching.weebly.com/earth-science.html


How is limestone Formed?

It can be formed in two ways:  by accumulation of living organisms and by evaporation.                                                                                                                                    Most limestones comes marine deposits, but some are formed in lakes, rivers and on land. When the organisms die, their shells are left on the ocean floor, lake bottom or river bed where they may accumulate into deposits.

Earth has many limestone-forming settings and most of them are found in shallow water, for instance in the Caribbean Sea, Indian Ocean, Persian Gulf, Gulf of Mexico and around Pacific Ocean islands.

      • Crinoidal Limestones: Crinoids are sea animals that had long stems, cup like bodies that look so much like flowers and for this reason called sea lillies. The stems breaks into small, disc shaped fragments. These are found extensively in eastern Kansas and Pennsylvania.
      • Fusilinid Limestones: The Fusilinid is one of the single-celled animals call Foraminifera. These small animals, whose shells look like wheat grains formed these kind of limestones.
    • Reef-like Limestones and Shell Limestones: These limestones contain the remains of corals, brachipods, clams, oysters, bryozoans and other forms. These deposits sometimes grow to several hundred miles in length.

A NASA satellite image of the Bahamas Platform where active limestone formation occurs today.
A NASA satellite image of the Bahamas Platform where active limestone formation occurs today.

image source: http://www.masonryworktools.com/whereislimestonefound.html


Limestone can also form through evaporation.                                                 Stalactites, stalagmites, and other cave formations (often called “speleothems“) are examples of limestone that formed through evaporation. In a cave, droplets of water seeping down from above enter the cave through fractures or other pore spaces in the cave ceiling. There they might evaporate before falling to the cave floor. Over time, this evaporative process can result in an accumulation of icicle-shaped calcium carbonate on the cave ceiling and it forms stalactites. If the droplet falls to the floor and evaporates there, it forms stalagmites that could grow upwards from the cave floor.

Voronya cave, in Georgia.
Voronya cave, in Georgia.

image source: https://www.erepublik.com/en/article/globe-trotter-in-georgia-2600234/1/20


Types of limestone

There are many different names used for limestone. These names are based upon how the rock formed, its appearance and its composition.

  • Chalk: A soft limestone with a very fine texture, generally white or light gray in color. It is formed usually from the calcareous shell remains of microscopic marine organisms.
  • Coquina: It is composed mainly of broken shell debris, formed on beaches where wave action fragment shells.
  • Fossiliferous Limestone: contains abundant fossils, normally shell and skeletal fossils of the organisms.
  • Lithographic Limestone: A dense limestone with a very uniform grain size which is very smooth surface.
  • Oolitic Limestone: is composed mainly of calcium carbonate “oolites,” small spheres formed by the concentric precipitation of calcium carbonate on a sand grain or shell fragment.
  • Travertine: A limestone formed through evaporation , often in a cave (stalactites, stalagmites, and flowstone).
  • Tufa: produced by precipitation of calcium-laden waters at a hot spring, lake shore, or other setting.
Varieties of limestone. Chalk (upper left) is a marine limestone consisting of tests of microscopic algae and foraminifera. Tufa (upper right) is a chemical precipitate of calcium carbonate. Fossils are very common in marine calcitic sedimentary rocks. Rocks such as coquina are wholly composed of fossils but so-called normal limestones may be also highly fossiliferous. The sample (lower left) is from the Ordovician. Grainstone is a coarse-grained grain-supported variety that contains almost no limy mud (micrite).
Varieties of limestone. Chalk (upper left) is a marine limestone consisting of tests of microscopic algae and foraminifera. Tufa (upper right) is a chemical precipitate of calcium carbonate. Fossils are very common in marine calcitic sedimentary rocks. Rocks such as coquina are wholly composed of fossils but so-called normal limestones may be also highly fossiliferous. The sample (lower left) is from the Ordovician. Grainstone is a coarse-grained grain-supported variety that contains almost no limy mud (micrite).

image source: http://www.sandatlas.org/limestone/


how was IT used THROUGHOUT history ?

Nobody knows exactly when humans first discovered limestone, however Lime foundations in eastern Turkey show that this was already being used 14,000 years ago. Earlier still, the Lascaux caves in France feature frescoes of natural iron oxide pigments applied to damp cave walls of high calcium content dating back as far as 16,000 years and it was also used to build the pyramids in Egypt. And Romans even would mix limestone with volcanic ash to form a type of material for building.

Frieze of the Small Horses a Lascaux cave, in France.
Frieze of the Small Horses a Lascaux cave, in France.

image source: http://www.bradshawfoundation.com/lascaux/lascaux_the_future.php

Some  limestone usage key dates:

    • c. 7500 B.C. The ancient people who lived in Jordan, made a plaster from lime to cover walls, floors and hearths in their homes.
    • c. 3000 B.C. The Egyptians built one of the limestone wonders of the world: the  Cheops pyramid.
    • Lime colors were featured in Greek frescos.
    •  500 B.C. The Chinese built the 2,500 km Great Wall and used lime mortars to cement the stones together.
    •  753 B.C. – 535 A.D. Roman frescos and buildings featured different lime colors. Women colored their hair to a light red hue with unslaked lime.
  • 16th Century Lime usage increased with evolutions in building and different types of structures.
  • 17th Century develop The Scagliola technique as substitute for marble inlays. It consistented a pigmented mixture of lime dust. It was also used to create building facades, stucco columns, sculptures and other architectural elements.
  • 18th& 19th Centuries Debray and Lechatelier discovered others qualities and applications of lime. For example, limestone was used for the first time as an ingredient in toothpaste.
  • 20th and 21st Centuries The rapid development of technologies, expanded the use of lime, which is why today, we encounter lime in lots of usage.

Becaus it is easily carved, Limestone, nowadays appears in many buildings, such as in the Empire State Building in New York City and on the U.S. Holocaust Memorial and Museum in Washington D.C.

Empire State Building made of Indiana limestone.
Empire State Building made of Indiana limestone.

image source: https://it.pinterest.com/Indiana200/buildings-made-from-indiana-limestone/


WHERE IT CAN BE FOUND TODAY?

Important uses of limestone also include:

  • Dimension Stone: Limestone is often cut into blocks of specific dimensions for building. It is used for facing stone, floor tiles, stair treads, window sills, and many other occasions.
  • Roofing Granules: Crushed to a fine particle size, limestone is used as a weather and heat-resistant coating on asphalt-impregnated shingles and roofing. It is also used as a top coat on built-up roofs.
    Flux Stone: Crushed limestone is even used in fusioning and other metal refining processes.
  • Portland Cement: Limestone is heated in a kiln with other materials and crushed in a powder that will harden after being mixed with water.
  • AgLime: Crushed to sand-size or smaller particles, limestone becomes an usefull material for treating acidic ground. It is also used on farms all over the world.
  • Lime: If calcium carbonate (CaC03) is heated to high temperature in a kiln, it produces carbon dioxide gas (CO2) and calcium oxide (CaO) which are used as an acid-neutralization for soil treatment in agriculture.
  • Animal Feed Filler: Chickens need calcium carbonate to produce strong egg shells, which is why it is often given to them as a dietary supplement in the form of “chicken grits.” Moreover, calcium is also given to some dairy cattle who must replace large amounts of calcium lost when they are milked.
  • Mine Safety Dust: Pulverized limestone is a white powder that can be sprayed onto surfaces of underground mine. This dust improves illumination and reduces the amount of coal dust that come up in the activity. In this way improves the breathed air  and it also reduces the risk of explosion produced by suspended particles of flammable coal dust in the air.
  • Limestone has finally many other uses; for instance in paper, paint, rubber, and plastics and as a sorbent of pollutants.

Limestone is an essential mineral commodity of national importance. Some of the many products made using limestone are shown in this photograph are breakfast cereal, paint, calcium supplement pills, a marble tabletop, antacid tablets, high-quality paper, white roofing granules, and Portland cement.
Limestone is an essential mineral commodity of national importance. Some of the many products made using limestone are shown in this photograph are breakfast cereal, paint, calcium supplement pills, a marble tabletop, antacid tablets, high-quality paper, white roofing granules, and Portland cement.

image source: http://geology.com/usgs/limestone/

info sources:

http://geology.com/rocks/limestone.shtml

https://www.irvmat.com/kids/whatIsLimestone.htm

http://sciencelearn.org.nz/Contexts/A-Fizzy-Rock/Science-Ideas-and-Concepts/Limestone-origins

http://people.ku.edu/~stalder/KS-limestone.html

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